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Easy Guide to Oily Water

Never dealt with oily water treatment before? You’re not alone, most of our customers will only select an oily water separator once in their career. Maybe you’ve seen it go wrong and want to make sure you don’t waste money on the wrong system. The information below should allow you to make an educated decision on what separator is right for your application.

1: The Four Types of Oil in Water

Oil contamination can be present in 4 different forms in water and each form requires a different treatment strategy.

You must know what types of oil pollution you have so that you can select the right treatment options.

 What is it?How can you treat it?

Free Oil


Oil droplets that are larger than 150 micron. Quickly forms an oil layer on the water surface.Skimming or gravity treatment is usually able to deal with free oil.

Emulsified Oil


Oil droplets smaller than 150 micron. The most common type of oil in most industries. There are 3 ways it can form: Chemically from degreasers, fuel additives and other types of surfactant. Mechanically due to pumps, valves etc. Biologically, if oil and water are stagnant for some time then bacteria will chew oil droplets into small peices.Requires a powerful separator. Cannot be removed by gravity.

Dissolved Oil


Oil droplets smaller than 2 micron, soluble oils and detergents. Not visible to the naked eye, water with dissolved oil will often appear clean. Biological activity can turn insoluble oil into soluble oil. Detergents are included in this category because most of the common tests for oil will show detergents as oil.Requires biological or chemical treatment. For example extended aeration. Cannot by removed by mechanical separators.

Heavy oil


Oil with a density greater than water. Also includes oil which has become stuck to heavy sediment.Won't be removed by many separators which require the oil to be lighter than the water

Not sure what mix of the 4 types of oil contamination you have? Let us help

Give us a call or send an email. We can use our experience and our extensive oily water database to get you started!

In addition you can take advantage of our extensive in-house oily water test facilities and laboratory. We are are able to analyse and characterise your oily water problem and give you a full report. In many cases we can do this for free!

2: Critical Oily Water Design Factors

There’s no ‘one size fits all’ oily water separator. Choosing an oil water separator without knowing what type of oily water it’s expected to treat is a recipe for disaster!

In the previous section we explained the different types of oil pollution you can experience in water, you can combine this knowledge with a few other key parameters listed below to accurately define the oily water that needs to be treated – this is typically called the influent.

Flow Rate

Why’s it important?

  • This will determine the size of separator you need.
  • If you have a low flow rate then you can install a more economical system. If you have a high flow rate then you will need a system which can keep up to avoid compliance issues and costly remediation.

Treatability

Why’s it important?

  • The harder it is to treat your water the more separation force you need to remove the oil.
  • Oil droplet size is the most important factor to determine the treatability of your water. Once you know the average oil droplet size in your water then you can determine which separator technologies can treat your water.

Oil Load

Why’s it important?

  • If there is a lot of oil coming into the system and your oil tank is too small then you can end up needing to empty it multiple times a day to stop the oil tank from overflowing.

Discharge Location

Why’s it important?

  • Where you intend to discharge your oily water will determine the treated water quality required.
  • Usually your local water authority will provide guidelines and limits based on where you want to discharge your water.

3: Oil Droplet Size

Oil Droplet Size

Why’s it important?

  • Oil droplet size determines how powerful your oily water separator needs to be
  • The smaller the average oil drops in your water are the more powerful you separator needs to be.
  • All types of oily water separator have different limitations on the droplet size that they can treat.

How do you measure it?

  • The most accurate way to work out the average oil droplet size is to measure it directly. This needs to be performed on site in real time. The droplet size in a static sample changes overtime so it won’t reflect the actual site conditions.
  • At Ultraspin we have a Video Particle Analyser which we use to determine droplet size. If you would like to know your droplet size then we can send one of our skilled technicians on-site with our particle sizer and measure it for you.
  • If you don’t have access to a particle sizer then you can estimate it from similar applications
  • Based on our testing across many different site we have produced the table to the right which shows approximate oil droplet size based on the application.
  • Check out our blog on oil droplet size for more detailed information on droplet size

Estimating Oil Droplet Size: Visually Compare Water Samples

You can also get a rough idea of your oil droplet size with a visual inspection of your sample. In general, if you can see the droplets with the naked eye, they are large, say 150 micron plus. If the water looks hazy, white or milky, the droplets are very small (less than 25 microns, often less than 10 micron). We have a data base of sample photos from thousands of applications with matching droplet sizes to give you a visual guide. Look for a sample that has similar characteristics to yours. If you need help, email us a photo of your sample and our oily water engineers will help you.

15 Micron
25 Micron
60 Micron
150 micron
15-micron
25-Micron
60-Micron
150-Micron
15-micron-sample
25-micron-sample
60-micron-sample
150-micron-sample

4: What Separator Can Treat my Oily Water

Now that you understand the 4 types of oil contamination; the particular mix of these type you have, and the importance of oil droplet size:

– you can begin to short list types of oil separator that might work for you

A good place to start is oil droplet sizes. You can narrow down your choice of oil separator technologies that suit your application based on what droplet size each separator technology is designed to treat.

Separator Technology Type300 micron150 micron60 micron25 micron15 micron
Ultraspin SeparatorsTick2Tick2Tick2Tick2Tick2
MembranesCross2Cross2Cross2Tick2Tick2
CentrifugesTick2Tick2Tick2Tick2Tick2
Media filtersCross2Tick2Tick2Cross2Cross2
Gas flotation with chemicalsCross2Tick2Tick2Tick2Tick2
Gas flotation without chemicalsCross2Tick2Tick2Cross2Cross2
Coalescing Plate Packs - VGSTick2Tick2Tick2Cross2Cross2
API gravity separatorTick2Tick2Cross2Cross2Cross2
European tanks / SPELTick2Tick2Cross2Cross2Cross2
Basic tanks, double or triple interceptorsTick2Tick2Cross2Cross2Cross2

5: Performance Guarantees

Oil Water Separator Performance Curves

Now that you understand the importance of oil droplet size you will now be able to understand Oil Separator Performance Curves. Many factors affect the performance of an oily water separator system installation. For most customers a primary consideration is oily water separation ability because this defines final discharge water quality or oil recovery rates. Oil Separation efficiency can be expressed as follows:

Oil Separator Efficiency (%) = 100 x ( Cin – Cout/ Cin)

  • Cin = feed inlet concentration (mg/l)
  • Cout = discharge outlet concentration (mg/l)

More powerful separators have a number of advantages including obtaining better quality discharge water, meet or exceed Local and National Trade Waste discharge standards, meet or exceed future discharge standards, deal with accidental oil spills, tolerate higher strength non-“quick-break” detergents and cleaners.

Oil Water separation efficiency can be objectively accessed by examining the separator oil droplet size vs. separation efficiency curves. For higher quality separators these curves should be readily available from manufacturers. Manufacturers should also be able to confirm performance to these curves by independent testing. The purpose of oily water separators is to obtain clean water. However, claims of a separator being able to achieve less than 10 mg/l discharge are meaningless and deceptive without recourse to oil droplet size performance curves.

s

Caution: There are oily water vendors who can’t measure the oil droplet size as they don’t own the specialised equipment required. You should not trust vendors who can’t measure oil droplet size. They can only guess how their equipment will work in your application.

It’s like a pressure vessel manufacturer not being able to measure pressure, or an oven manufacturer not being able to measure temperature.  It’s ridiculous – but it happens!

Always ask your supplier for an objective oil droplet based performance curve like the one shown here. Make sure its one they have generated by measuring oil droplet size on their equipment, and not copied from another vendor like Ultraspin. Compare the curve to the oil droplet size you have or need. If a supplier can’t or won’t send you their own performance curve – be very wary!

6: Other Oily Water Fluid properties

Mean oil droplets size is the single most important factor for defining the dirty oil water, but there are several other factors that are also important.

Temperature Sym
Temperature Sym
Temperature Sym

Temperature

The viscosity of the water falls as the water temperature rises. This allows oil droplets to move more easily through the water phase, thereby producing better oil separation with many oil water separators (but not all). Therefore, increased temperature improves separation efficiency for most oily water separators. The Ultraspin separator can be supplied to operate within the temperature range 0 to 120°C (32 to 248°F), at higher temperatures special materials may be required.

Oil Water Separators that work better at higher temperatures include:

  • Coalescing plate packs (5 to 80 oC)
  • Ultraspin Separators (5 to 120 oC)
  • Gravity tanks and vessels (5 to 90 oC)
  • Centrifuges (5 to 90 oC)

Oil water separators that may not separate as effectively at higher temperatures include:

  • Air flotation devices (DAF, CAL, IGF) (5 to 30 oC)
  • Media filters (5 to 45 oC)
  • Membranes (5 to 65 oC)
  • These types of separator may require water coolers to work effectively.

Density Difference

For many oil water separators the oil removal efficiency is dependent on the difference in density between the contaminant and the water. The separation efficiency increases as the difference in density increases. The density difference can increase if you have lighter oils or your water is salty, or both. Typical densities for Oil are 950 to 750 kg/m3 (0.034 to 0.027 lb/in3) and water : 1050 to 995 kg/m3.(0.038 to 0.036 lb/in3).

For these types of oily water separator performance improves as the density difference increases, and generally the density difference must generally be more than 25 kg/m3

  • Coalescing plate packs
  • Gravity tanks / SPEL / Triple and double interceptors
  • Ultraspin Separators

For these types of oil water separators are not greatly effected by small density differences (say less than 25 kg/m3):

  • Media filters
  • Membranes
  • Air flotation (DAF, IAF, CAF)

Inlet Concentration

Some types of oil water separator are NOT well suited to high oil feed concentrations and high feed oil concentrations overload or block the systems. For these types of system careful pre-treatment to remove oil will be required.

  • Coalescing plate packs (max 1% oil or 10,000 mg/l).
    • With high oil concentration for this type of separator the plates become coated in oil and sludge. This requires the plates to be removed and cleaning to restore oil removal efficiency.
  • Air flotation systems (DAF, IAF, CAF) (max 1% oil or 10,000 mg/l)
  • Media filters (typical max 100 mg/l oil )
  • Membranes (typical max 300 mg/l)

Other types of system can accommodate 100% oil concentration for a period of time:

  • Ultraspin systems
  • Centrifuges
  • Gravity tanks / SPEL / Triple and double interceptors
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